The documented process is not the process
Every organisation has a process document, and the work does not follow it.
This is not a failure of discipline. Documents describe the intended path, and real work contains exceptions, informal shortcuts, undocumented handoffs, and steps that exist because of something that happened three years ago. The gap is largest in exactly the processes people most want to automate, because complexity is what made them slow.
So the first work is observation rather than design. Sit with the people doing the task. Follow individual items through end to end. Ask why at each step and record the answers, because a step whose reason nobody remembers is either removable or load-bearing in a way you need to discover before removing it.
Two specific things to look for.
The unofficial steps. The spreadsheet someone maintains, the message they send to check something, the second system they cross-reference. These rarely appear in documentation and frequently carry the process.
And the exception paths. The documented flow describes the common case; the time is often spent elsewhere. If thirty percent of items take a different route, a redesign optimising the other seventy percent will disappoint.
Mapping badly is the most common reason a redesign fails to deliver, and it is entirely preventable.

